References - Publications
Litos Lite is a parallel JV and stability measurement platform for the measurement of organic and perovskite solar cells. Below you will find references from our customers who are using Litos Lite as well as the work they have published.
“Recently, we received a Litos Lite with 56 channels. I am so glad that the instrument integrates an LED-based sun simulator. This is far more convenient than replacing Xenon bulbs all the time. The custom-made sample holders work for our 3 different sample layouts, and with the parallel JV characterization and MPPT, we are saving a lot of time. I also appreciate the good support received by the Fluxim team.”
Dr . Justin Chen, Reinhold Dauskardt Group, Stanford University
LITOS LITE is highly recommended!
We have one in our labs and we are saving hours of work by measuring many samples at one time. No time to build our setup up so this was a great purchase!
Prof. Juan-Pablo Correa-Baena, Leader of the Energy Materials Lab, Materials Science and Engineering at Georgia Tech, USA
5 star recommendation for LITOS LITE and FLUXIM support. A great choice for my lab, for setting up a nicely working system for monitoring stability under different conditions of our perovskite solar cells! Great communication with FLUXIM for installation, training and support! Highly recommended!
Prof. Giulia Grancini
Director of ERC HYNANO project and pvsquared2 team and University of Pavia, Italy
Litos Lite Publications
Raphael F. Moral, Carlo A. R. Perini*, Tim Kodalle, Ahyoung Kim, Finn Babbe, Nao Harada, Javid Hajhemati, Philip Schulz, Naomi S. Ginsberg, Shaul Aloni, Craig P. Schwartz, Juan-Pablo Correa-Baena*, and Carolin M. Sutter-Fella*
ACS Energy Lett. 2024, 9, 6, 2703–2716
Publication Date: May 14, 2024
https://doi.org/10.1021/acsenergylett.4c00728
This study investigates ionic dynamics at 2D/3D halide perovskite interfaces in solar cells, revealing that light and heat induce ion migration. Phenethylammonium halide salts enhance efficiency and stability, with specific migration patterns and phase distributions observed under thermal treatment, impacting photovoltaic performance.
How Litos Lite was used
The photovoltaic performance assessment was conducted utilizing a Fluxim Litos Lite arrangement, which featured a Wavelabs Sinus-70 AAA solar simulator that produced an AM1.5 spectrum for excitation purposes. The current−voltage (J−V) attributes were obtained through both forward and reverse scans, each performed at a scan rate of 50 mV s−1. Stabilized power output measurements were completed utilizing a maximum power point (MPP) tracking algorithm over a span of 60 s.
Sami Toikkonen, G. Krishnamurthy Grandhi, Shaoyang Wang, Bora Baydin, Basheer Al-Anesi, L. Krishnan Jagadamma, Paola Vivo.
Adv Devices Instrum.2024;5:0048.
The study investigates the necessity of doping Spiro-OMeTAD in lead halide perovskite (LHP) indoor photovoltaics (IPVs). It concludes that undoped Spiro-OMeTAD can achieve high efficiency and stability under low-light conditions, rivaling doped counterparts, suggesting that dopants may not be essential for effective IPV performance.
How Litos Lite was used
Litos Lite was utilized to perform J–V reverse and forward sweeps (scan rate 50 mV s−1), maximum power point (MPP) tracking, and stable power output (SPO) measurements on the prepared photovoltaic cells. These measurements were conducted under both simulated sunlight (AM 1.5G, 1-Sun, 100 mW cm−2) and indoor WLED illumination (5,000 lux, ≈1.60 mW cm−2) in N2 atmosphere. The indoor MPP tracking was performed either under continuous illumination or in 8-hour light–16-hour dark cycles .
How Paios was used
Transient photovoltage and transient photocurrent measurement were carried out with the all-in-one characterization platform, Paios.
Rohit D. Chavan, Bartłomiej Bończak, Joanna Kruszyńska, Apurba Mahapatra, Muhammad Ans, Jan Nawrocki, Kostiantyn Nikiforow, Pankaj Yadav, Jan Paczesny, Faranak Sadegh, Muhittin Unal, Seckin Akin, and Daniel Prochowicz
Chemistry of Materials 2023 35 (19), 8309-8320
DOI: 10.1021/acs.chemmater.3c01995
This study introduces a novel azahomofullerene (AHF-4) as an interlayer in perovskite solar cells (PSCs), enhancing charge transfer and film quality while reducing recombination. AHF-4 outperforms the standard fullerene derivative PCBM, achieving higher efficiency (21.43%) and better stability under light and heat, promising advancements in PSC performance and durability.
How Litos Lite and Litos were used
The photovoltaic performance was evaluated using a Fluxim Litos Lite setup, equipped with a Wavelabs Sinus LS2 solar simulator with AM 1.5 spectrum for excitation.
Aging tests were also performed using a Fluxim Litos setup, and 1 Sun equivalent illumination with no UV component, holding the substrates at 45 ± 5 °C in a N2 atmosphere and using an MPP tracking algorithm.
Montecucco, R., Pica, G., Romano, V., De Boni, F., Cavalli, S., Bruni, G., Quadrivi, E., De Bastiani, M., Prato, M., Po, R. and Grancini, G. (2023),
Sol. RRL 2300358.
https://doi.org/10.1002/adfm.202306040
All-inorganic perovskites show potential for creating stable and high-performing perovskite solar cells (PSCs). But, the high annealing temperature required for CsPbI3 stabilization limits its scalability for industrial production. This research introduces a method to stabilize CsPbI3ₓBrx perovskite at a reduced annealing temperature of 180°. This is achieved by using dimethylammonium (DMA) additives and bromide, facilitating the conversion to CsPbI3ₓBrx. Solar cells produced this way reached a power conversion efficiency (PCE) of 14.86%, outperforming the reference device. Using different halides in DMA salt for higher temperature annealing also proved beneficial, yielding an impressive PCE of 16.23%. This method, by lowering processing temperature, extends the utility of all-inorganic PSCs for industrial use and temperature-sensitive materials.
How Litos Lite was used
The stability measurements were performed at the MPP under N2 inert atmosphere and ambient temperature using Litos Lite coupled with a solar simulator continuously illuminating the devices. The spectrum used for the stability measurements was the same as the current density–voltage measurements.
Juanita Hidalgo, Lahoucine Atourki, Ruipeng Li, Andrés-Felipe Castro-Méndez, Sanggyun Kim, Emmet A. Sherman, Alexander S. Bieber, Meng-ju Sher, Lea Nienhaus, Carlo A.R. Perini, Juan-Pablo Correa-Baena,
Materials Today, Volume 68, 2023, Pages 13-21, ISSN 1369-7021,
https://doi.org/10.1016/j.mattod.2023.06.010
Interfacial treatments using bulky cations on 3D lead halide perovskites (LHPs) have led to over 25% power conversion efficiencies, but the reasons for this boost remain unclear. This study zeroes in on formamidinium lead iodide (FAPI) perovskites and shows that phenethylammonium iodide (PEAI) prevents the FAPI from changing into less desirable hexagonal forms in air exposure. Using advanced analytical methods, researchers discovered that untreated FAPI films predominantly show these undesired hexagonal phases. However, when coated with PEAI, FAPI films exhibit improved carrier lifetimes and photoconductivity. Such PEAI-treated FAPI solar cells can achieve up to 20.2% efficiency and 1.14 V open circuit voltages, marking one of the top performances for FAPI cells without extra cations.
How Litos Lite was used
Solar cell performance was evaluated under a solar simulator LITOS LITE from Fluxim, with AM1.5 spectrum, same light intensity for the maximum power point tracking for 180 s. The current density–voltage (JV) curve was measured in a forward and reverse bias at a scan rate of 50 mV/s. The cells were masked for measurement with a pixel area of 0.0625 cm2. Nitrogen was flown in the measurement chamber during characterization.
Larini, V., Ding, C., Faini, F., Pica, G., Bruni, G., Pancini, L., Cavalli, S., Manzi, M., Degani, M., Pallotta, R., De Bastiani, M., Ma, C.-Q., Grancini, G
Adv. Funct. Mater. 2023, 2306040.
https://doi.org/10.1002/adfm.202306040
Transparent conductive oxide (TCO)-coated glasses are a costly and environmentally impactful part of perovskite solar cells (PSCs), accounting for 56% of their total cost and 96% of their carbon footprint. Recycling TCO glasses from old PSC modules can reduce both their cost and energy payback time. In this study, tin oxide (SnO2)-coated indium tin oxide glasses are refurbished using eco-friendly dimethyl sulfoxide as a solvent. The reclaimed substrates are used to create new-generation PSCs with the same high efficiency of 22.6%, and even higher average efficiency, thanks to surface modifications and trap passivation on the SnO2/perovskite interface.
How Litos Lite was used
Stability measurements were conducted by coupling a WavelabsSINUS-70 solar simulator with a Fluxim Litos Lite module and perform-ing maximum power point tracking for 1000 h under an N2atmosphere at1 sun illumination, employing a shadow mask of 1.25 mm2active area.
Juanita Hidalgo, Yu An, Dariia Yehorova, Ruipeng Li, Joachim Breternitz, Carlo A.R. Perini, Armin Hoell, Pablo P. Boix, Susan Schorr, Joshua S. Kretchmer, and Juan-Pablo Correa-Baena
Chemistry of Materials 2023 35 (11), 4181-4191
DOI: 10.1021/acs.chemmater.3c00075
This scientific article investigates the factors that determine crystallographic orientation in lead bromide perovskites. The researchers show that the solvent and organic A-site cation play a critical role in preferred orientation of the thin films. The results reveal that the solvent, specifically dimethylsulfoxide (DMSO), influences the early stages of crystallization and induces preferred orientation by preventing colloidal particle interactions. Additionally, the choice of A-site cation, such as methylammonium or formamidinium, affects the degree of preferred orientation. Density functional theory calculations suggest that the difference in surface energy between the (100) and (110) facets is the reason for the varying degrees of preferred orientation. Besides, the researchers observe that the choice of A-site cation impacts ion density and accumulation, leading to increased hysteresis in solar cells. Overall, this study highlights the importance of solvent and A-site cation in determining crystallographic orientation and its impact on the electronic and ionic properties of solar cells.
How Litos Lite & Paios were used
LITOS LITE was used to measure the current density-voltage (J-V) characteristics of the solar cells. The J-V curves were obtained by scanning voltage in the range from 1.4 to -0.5 V with a scan speed of 50 mV·s-1 first in reverse and then in forward scan directions. The active area of the device was 0.128 cm2, and a black metal mask with an aperture area of 0.0625 cm2 was used to define the illuminated area.
Impedance Spectroscopy: #PAIOS was used to perform Impedance Spectroscopy (IS) on complete solar cells at room temperature under one sun illumination and in ambient air. The measurements were performed at five different offset voltages spaced from 0 V to the open circuit.
Carlo Andrea Riccardo Perini, Esteban Rojas-Gatjens, Magdalena Ravello, Andrés-Felipe Castro-Mendez, Juanita Hidalgo, Yu An, Sanggyun Kim, Barry Lai, Ruipeng Li, Carlos Silva-Acuña, and Juan-Pablo Correa-Baena
Adv. Mater. 2022, 34, 2204726
https://doi.org/10.1002/adma.202204726
This study investigates the impact of bulky-cation-modified interfaces on the stability of halide perovskite solar cells, which has not been extensively explored. The research demonstrates the thermal instability of these interface layers used in state-of-the-art solar cells and reveals changes in the chemical composition and structure of the films under thermal stress, which affects charge-carrier dynamics and device operation. The type of cation used for surface treatment also affects the extent of these changes, with long carbon chains providing more stable interfaces. The study emphasizes the importance of prolonged annealing of the treated interfaces to enable reliable reporting of performance and inform the selection of different bulky cations.
Device Characterization: The photovoltaic performance was evaluated using a Fluxim Litos Lite setup, equipped with a Wavelabs Sinus-70 AAA solar simulator with AM1.5 spectrum for excitation.
Aging tests were performed using a Fluxim Litos setup, using 1 Sun equivalent illumination with no UV-component, holding the substrates at 55 °C in a N2 atmosphere and using an MPP tracking algorithm. Every 12 h, a J–V scan in reverse and forward direction was automatically acquired.
Andrés-Felipe Castro-Méndez, Carlo A. R. Perini, Juanita Hidalgo, Daniel Ranke, Jacob N. Vagott, Yu An, Barry Lai, Yanqi Luo, Ruipeng Li, and Juan-Pablo Correa-Baena
ACS Applied Materials & Interfaces Article ASAP
Thermal evaporation is a promising deposition technique to scale up perovskite solar cells (PSCs) to large areas, but the lack of understanding of the mechanisms that lead to high quality evaporated methylammonium lead triiodide (MAPbI3) films gives rise to devices with efficiencies lower than those obtained by spin coating.
In this paper the researchers investigate the role of Sr and Ca additives to CsFA-PbI solar cells on performance.
Litos Lite was used to perform JV scan under 1 sun illumination.
Hurriyet Yuce, Diana LaFollette, Mustafa M. Demir, Carlo A.R. Perini, Juan-Pablo Correa- Baena
Sol. RRL 2100999.
doi.org/10.1002/solr.202100999
In the article the researchers investigate the crystal formation of co-evaporated MAI -PbI2 films at different temperature on the Perovskite Solar Cell (PSC) performance and correlate it to the occurrence of different phases.
The J-V curves of the devices were measured in a forward and reverse bias under the solar simulator (Fluxim, Litos Lite) with AM1.5 spectrum at a scan rate of 15 mV/s.
Perini, Carlo and Rojas-Gatjens, Esteban and Ravello, Magdalena and Castro Mendez, Andres Felipe and Hidalgo, Juanita and An, Yu and Li, Ruipeng and Silva-Acuña, Carlos and Correa-Baena, Juan-Pablo
10 Sep 2021
The impact on device stability of the bulky cation-modified interfaces in halide perovskite solar cells is not well-understood. In this paper the research team demonstrate the thermal instability of the bulky cation interface layers used in some of the highest performing solar cells to date.
The photovoltaic performance was evaluated using a Fluxim Litos Lite setup, equipped with a Wavelabs Sinus-70 AAA solar simulator with AM1.5 spectrum for excitation. The current voltage (J-V) characteristics were acquired with forward and reverse scans at a scan rate of 50 mV s-1. The stabilized power output was acquired using a maximum power point tracking algorithm for 60 s. Devices were not preconditioned before measurement. Masking was used during the measurement, defining a pixel area of 0.0625 cm2. Nitrogen was flown in the measurement chamber during characterization. No temperature control was applied. Aging tests were performed using a Fluxim Litos setup, using 1 Sun equivalent illumination with no UV-component, holding the substrates at 55 °C in a N2 atmosphere and using a maximum power point tracking algorithm. Every 12 h a J-V scan in reverse and forward direction was automatically acquired.